The Cu and NiAl nanoscale precipitation and interfacial segregation in the martensite and austenite phases within a high-strength steel were studied by atom-probe tomography (APT). In the martensite phase, APT reveals the precipitation of isolated NiAl nanoparticles and NiAl/Cu co-precipitates, indicating that NiAl nanoparticles form first in the precipitation sequence. In comparison, the austenite phase contains only Cu nanoparticles with Ni segregation at the particle/matrix interface, in which the Ni segregation reduces the Cu nanoparticle interfacial energy. In addition, Mn and C exhibit an enrichment at the martensite/austenite interface, and the mechanism for the interfacial segregation was also discussed.
IMPACT STATEMENTThe understanding of nanoscale precipitation and interfacial segregation mechanism provides the basis for the control of precipitate microstructures and mechanical properties of nanoparticlestrengthened steels.
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