“…Notably, some variations in the peak shape (widening) and positions (6.58°, 18.1°, 35.2°, 62.1°) are slightly shifted in the direction of the decreasing diffraction angle; such phenomena are related to the grain size, lattice distortion and residual stresses (microscopic and macroscopic). [25][26][27] This is because of the influence of different ion/composition changes on the crystalline phase. Ions with larger radii replace those with smaller radii in the structure, resulting in an increase in the lattice spacing, causing the peak shape and position to accordingly change.…”