Ag-TiO 2 nanostructured thin films with silver volume fraction of 0-20% were deposited on silicon and quartz substrates by RF magnetron sputtering and annealed in ambient air at 950°C for 1 h. The phase structure and surface topography of the films were characterized by X-ray diffractometer and transmission electron microscope. Photocatalytic activity of the films was evaluated by light induced degradation of methyl orange (C 14 H 14 N 3 NaO 3 S) solution using a high pressure mercury lamp as lamp-house. The relation of photocatalytic activity and silver content was studied in detail. It was found that silver content influences phase structure of TiO 2 thin films, and silver in the films is metallic Ag (Ag 0 ). With increasing silver content from 0 to 20 vol%, photocatalytic activity of the films increases first and then decreases. A suitable amount (2.5-5 vol%) silver addition can significantly enhance the photocatalytic activity of TiO 2 films. The enhanced photocatalytic activity was mainly attributed to the extension of visible light absorption region of the films, the presence of anatase phase, the increase of oxygen anion radicals 2 O − and reactive center of surface Ti 3+ , and the better separation between electrons and holes on the films surface.silver, nanoparticle, TiO 2 thin film, photocatalytic activity, RF magnetron sputtering, methyl orange
Citation:Meng F M, Lu F, Sun Z Q, et al. A mechanism for enhanced photocatalytic activity of nano-size silver particle modified titanium dioxide thin films.