“…When the grain size is very small, these fine particles have sizes similar to the grain size, and it may be better to consider the material as a composite mixture of matrix grains and particles. Orowan hardening by fine particles, size s, present in volume fraction f in a material of grain size d >> f, can be described as: (13) where m is the Taylor factor, G the shear modulus, b the Burgers vector and l the separation of particles on the shear plane [65] . Since particles tend to pin grain boundaries, grain size and particle size are often related, for example by the Zener relation, d = 0.66 f/√f, grain size and particle separation may be related: (14) Orowan strengthening models can clearly only be used for materials with a small volume fraction of second phase, say less than 10 %, but are independent of grain size.…”