Microstructure and Wear Behavior of Atmospheric Plasma-Sprayed AlCoCrFeNiTi High-Entropy Alloy Coating

Tian, Lihui; Xiong, Wei; Liu, Chuan; Lu, Sheng; Fu, Ming

doi:10.1007/s11665-016-2396-6

Cited by 105 publications

(50 citation statements)

References 29 publications

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“…It was indicated that the hardness of the APS coating could be degraded by the microstructure defects, such as the pores and the interface between the metal phase and oxide stringers. Similar research results also were reported by Guo et al and Tian et al [46,47]. Figure 9 indicated that the wear resistance of the APS coating was an order of magnitude higher than that of HVOF coating.…”

Section: Tribological Behaviorsupporting

confidence: 88%

Microstructure and Wear Behavior of FeCoCrNiMo0.2 High Entropy Coatings Prepared by Air Plasma Spray and the High Velocity Oxy-Fuel Spray Processes

Liu

et al. 2017

Coatings

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Abstract:In the present research, the spherical FeCoCrNiMo0.2 high entropy alloy (HEA) powders with a single FCC solid solution structure were prepared by gas atomization. Subsequently, the FeCoCrNiMo0.2 coatings with a different content of oxide inclusions were prepared by air plasma spraying (APS) and high-velocity oxy-fuel spraying (HVOF), respectively. The microstructure, phase composition, mechanical properties, and tribological behaviors of these HEA coatings were investigated. The results showed that both HEA coatings showed a typical lamellar structure with low porosity. Besides the primary FCC phase, a mixture of Fe 2 O 3 , Fe 3 O 4 , and AB 2 O 4 (A = Fe, Co, Ni, and B = Fe, Cr) was identified as the oxide inclusions. The oxide content of the APS coating and HVOF coating was calculated to be 47.0% and 12.7%, respectively. The wear resistance of the APS coating was approximately one order of magnitude higher than that of the HVOF coating. It was mainly attributed to the self-lubricated effect caused by the oxide films. The mass loss of the APS coating was mainly ascribed to the breakaway of the oxide film, while the main wear mechanism of the HVOF coating was the abrasive wear.

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Section: Tribological Behaviorsupporting

confidence: 88%

Microstructure and Wear Behavior of FeCoCrNiMo0.2 High Entropy Coatings Prepared by Air Plasma Spray and the High Velocity Oxy-Fuel Spray Processes

Liu

et al. 2017

Coatings

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“…HEAs are defined as alloys containing at least five major elements wherein every major element has an atomic fraction between 5% and 35% [9]. Various studies on HEAs, including composition, processing, crystal structure and microstructure, and physical and mechanical properties, have been performed in the past years [5,6,7,8,9,10,11,12,13,14,15,16,17,18,19,20,21,22,23]. …”

Section: Introductionmentioning

confidence: 99%

Compositional Dependence of Phase Selection in CoCrCu0.1FeMoNi-Based High-Entropy Alloys

et al. 2018

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To study the effect of alloy composition on phase selection in the CoCrCu0.1FeMoNi high-entropy alloy (HEA), Mo was partially replaced by Co, Cr, Fe, and Ni. The microstructures and phase selection behaviors of the CoCrCu0.1FeMoNi HEA system were investigated. Dendritic, inter-dendritic, and eutectic microstructures were observed in the as-solidified HEAs. A simple face centered cubic (FCC) single-phase solid solution was obtained when the molar ratio of Fe, Co, and Ni was increased to 1.7 at the expense of Mo, indicating that Fe, Co, and Ni stabilized the FCC structure. The FCC structure was favored at the atomic radius ratio δ ≤ 2.8, valence electron concentration (VEC) ≥ 8.27, mixing entropy ΔS ≤ 13.037, local lattice distortion parameter α2 ≤ 0.0051, and ΔS/δ2 > 1.7. Mixed FCC + body centered cubic (BCC) structures occurred for 4.1 ≤ δ ≤ 4.3 and 7.71 ≤ VEC ≤ 7.86; FCC or/and BCC + intermetallic (IM) mixtures were favored at 2.8 ≤ δ ≤ 4.1 or δ > 4.3 and 7.39 < VEC ≤ 8.27. The IM phase is favored at electronegativity differences greater than 0.133. However, ΔS, α2, and ΔS/δ2 were inefficient in identifying the (FCC or/and BCC + IM)/(FCC + BCC) transition. Moreover, the mixing enthalpy cannot predict phase structures in this system.

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“…The mixed powders were put into a vacuum oven at 80°C to dry for 1 h after vacuum ball milling in order to remove moisture and enhance the liquidity of the powder. The plasma spraying technology [27] was adopted in the preparation of the FeCoCrNiB x HEA coatings. An appropriate amount of alcohol was taken as the adhesive and mixed with the aforementioned ball milling powder to obtain the viscous powder, which was coated on the Q245R steel matrix with a coating size of 32 mm × 10 mm × 1.6 mm.…”

Section: Methodsmentioning

confidence: 99%

Effects of Boron Content on Microstructure and Wear Properties of FeCoCrNiBx High-Entropy Alloy Coating by Laser Cladding

Liu

Zhao

et al. 2019

Applied Sciences

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The FeCoCrNiBx high-entropy alloy (HEA) coatings with three different boron (B) contents were synthesized on Q245R steel (American grade: SA515 Gr60) by laser cladding deposition technology. Effects of B content on the microstructure and wear properties of FeCoCrNiBx HEA coating were investigated. In this study, the phase composition, microstructure, micro-hardness, and wear resistance (rolling friction) were investigated by X-ray diffraction (XRD), a scanning electron microscope (SEM), a micro hardness tester, and a roller friction wear tester, respectively. The FeCoCrNiBx coatings exhibited a typical dendritic and interdendritic structure, and the microstructure was refined with the increase of B content. Additionally, the coatings were found to be a simple face-centered cubic (FCC) solid solution with borides. In terms of mechanical properties, the hardness and wear resistance ability of the coating can be enhanced with the increase of the B content, and the maximum hardness value of three HEA coatings reached around 1025 HV0.2, which is higher than the hardness of the substrate material. It is suggested that the present fabricated HEA coatings possess potentials in application of wear resistance structures for Q245R steel.

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Microstructure and Wear Behavior of Atmospheric Plasma-Sprayed AlCoCrFeNiTi High-Entropy Alloy Coating

Cited by 105 publications

References 29 publications

Microstructure and Wear Behavior of FeCoCrNiMo0.2 High Entropy Coatings Prepared by Air Plasma Spray and the High Velocity Oxy-Fuel Spray Processes

Microstructure and Wear Behavior of FeCoCrNiMo0.2 High Entropy Coatings Prepared by Air Plasma Spray and the High Velocity Oxy-Fuel Spray Processes

Compositional Dependence of Phase Selection in CoCrCu0.1FeMoNi-Based High-Entropy Alloys

Effects of Boron Content on Microstructure and Wear Properties of FeCoCrNiBx High-Entropy Alloy Coating by Laser Cladding

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