Titanium and some of its alloys have become increasingly important for biomedical materials due to their high specific strength, good corrosion resistance, and excellent biocompatibility compared to the biomedical stainless steels and cobalt-chromium based alloys. In this study, a b type TTHZ alloy (Ti-40Ta-22Hf-11.7Zr) was prepared with the cold-crucible levitation technique. The corrosion behavior and the effects of solution treatment (ST) and aging on the microstructures and mechanical properties of the TTHZ alloy were investigated using electrochemical analysis, XPS (X-ray photoelectron