Numerous methods are known for generating micron-scale closed-cell and open-cell porosity in
organic coatings and thin films. One formulation technique, known as the solvent precipitation
method, is effective at producing a wide range of structures of commercial interest. Useful
physical properties include enhanced light reflectance, open-cell porosity, microencapsulation,
reduced density, and thermal insulation. These desirable properties have been applied
commercially to prepare artificial leather, battery separators, paper coatings, light reflectance
standards, insulative coatings, coatings and inks with improved hiding, controlled-release films,
low-density flexible circuit boards, and membranes. This paper will review formulation strategies
and commercial applications for microporous films via the solvent precipitation method with
emphasis on the U.S. patent literature since 1970.