“…tions [18,24,27,44,54,55,57,69,70,133,139]. The presence of Al 4 C 3 has been identified by XRD in some cases [18,27,55,102,133], while in other cases, XRD was not able to detect any interfacial reactions, such as forming the Al 4 C 3 [24,44,54,69,70,94]. The undetectability of Al 4 C 3 by XRD was attributed to the low content of carbides formed, making it beyond the detection limit of XRD; the absence of any residual carbon in the starting reinforcement material; and the passivation of Al due to the formation of thin stable aluminum oxide preventing any chemical contact between Al and carbon.…”