Microwave assisted batch and continuous flow Suzuki–Miyaura reactions in GVL using a Pd/PiNe biowaste-derived heterogeneous catalyst

Valentini, Federica; Di Erasmo, Benedetta; Ciani, Marta; Chen, Shaomin; Gu, Yanlong; Vaccaro, Luigi

doi:10.1039/d4gc00497c

Search citation statements

Order By: Relevance

Paper Sections

Select...

Introduction1

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

2025

Publication Types

Select...

Article4

Relationship

Self Cite1

Independent3

Authors

Journals

Cited by 4 publications

(1 citation statement)

References 133 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

“…We believe that a significant advance in sustainability for the specific synthesis of HABs can be achieved by combining the advantages of flow chemistry with the possibility of using an environmentally benign reaction medium. 40–45…”

Section: Introductionmentioning

confidence: 99%

Efficient access to hexaaryl-substituted borazines in batch and continuous-flow

Nazari Khodadadi,

Cela,

Marchionni

et al. 2024

Green Chem.

Self Cite

View full text Add to dashboard Cite

show abstract

Section: Introductionmentioning

confidence: 99%

Efficient access to hexaaryl-substituted borazines in batch and continuous-flow

Nazari Khodadadi,

Cela,

Marchionni

et al. 2024

Green Chem.

Self Cite

View full text Add to dashboard Cite

show abstract

Ni/PiNe Heterogeneous Catalyst from Biomass Waste: Low‐Loading, Ligand‐Free Suzuki‐Miyaura Cross‐Coupling

Valentini,

Chen,

Brufani

et al. 2024

ChemSusChem

View full text Add to dashboard Cite

An efficient Ni‐based heterogeneous catalyst from pine needles urban waste valorization was designed and developed with a resource recycling strategy. The Ni/PiNe catalyst was fully characterized and tested in the Suzuki‐Miyaura coupling under microwave irradiation. Although Ni is a promising candidate for replacing Pd‐based catalytic systems, it generally requires a high catalyst amount and the exploitation of ligands and additives to enhance the reaction rate. On the contrary, with our new Ni/PiNe, 30 different products were efficiently synthesized with an isolated yield of up to 93%, using a very low catalyst amount and in the absence of ligands. Furthermore, the Ni/PiNe catalyst also showed good durability for consecutive cycles and an impressive TON value (1140). In addition to the catalytic efficiency in short reaction time and to the stability and durability under MW irradiation, the Ni/PiNe allowed for further optimization, achieving a low E‐factor value (14.0), thus highlighting the potential in further reducing the waste and costs associated to the process.

show abstract

Exploring Carbon-based Materials as a tailored platform for Suzuki–Miyaura Coupling Reaction: A Review

Jabeen,

Li,

et al. 2025

Coordination Chemistry Reviews

View full text Add to dashboard Cite

Microwave assisted batch and continuous flow Suzuki–Miyaura reactions in GVL using a Pd/PiNe biowaste-derived heterogeneous catalyst

Abstract: Aiming at the definition of alternative and low-impact synthetic pathways, we herein reported the exploitation and the simultaneous employment of different tools to improve the overall sustainability of Suzuki-Miyaura cross-coupling...

Cited by 4 publications

References 133 publications

Efficient access to hexaaryl-substituted borazines in batch and continuous-flow

Efficient access to hexaaryl-substituted borazines in batch and continuous-flow

Ni/PiNe Heterogeneous Catalyst from Biomass Waste: Low‐Loading, Ligand‐Free Suzuki‐Miyaura Cross‐Coupling

Exploring Carbon-based Materials as a tailored platform for Suzuki–Miyaura Coupling Reaction: A Review

Contact Info

Product

Resources

About