2011
DOI: 10.1016/j.matchemphys.2011.02.032
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Microwave-assisted facile and rapid synthesis of self-assembled conducting copolymer nanorods via aqueous/ionic liquid interfacial polymerization

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Cited by 18 publications
(7 citation statements)
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“…97 Haldorai et al described IP as a reliable non-template approach with an easy synthesis and economic viability for synthesizing poly(anilineco-p-phenylenediamine) [ poly(Ani-co-p-PD)] nanorods via a microwave-assisted aqueous-ionic liquid interfacial oxidative polymerization in the presence of acid dopants. 98 Du et al have reported the formation of PANI nanotubes under various synthesis conditions without templates. 99 Nuraje et al also described the interfacial crystallization of conductive polymers at the liquid-liquid interface, allowing PANI and PPy polymers to form single crystalline nanocrystals in a rice-like shape in the dimensions of 63 nm × 12 nm for PANI and 70 nm × 20 nm for PPy.…”
Section: Template-free Synthesismentioning
confidence: 99%
“…97 Haldorai et al described IP as a reliable non-template approach with an easy synthesis and economic viability for synthesizing poly(anilineco-p-phenylenediamine) [ poly(Ani-co-p-PD)] nanorods via a microwave-assisted aqueous-ionic liquid interfacial oxidative polymerization in the presence of acid dopants. 98 Du et al have reported the formation of PANI nanotubes under various synthesis conditions without templates. 99 Nuraje et al also described the interfacial crystallization of conductive polymers at the liquid-liquid interface, allowing PANI and PPy polymers to form single crystalline nanocrystals in a rice-like shape in the dimensions of 63 nm × 12 nm for PANI and 70 nm × 20 nm for PPy.…”
Section: Template-free Synthesismentioning
confidence: 99%
“…The interfacial polymerization of aniline in a water/IL system resulted in Pani nanoparticles with 30e80 nm and conductivity of about 7 Â 10 À2 S/cm, by using 1-butyl-3-methyl-imidazolium hexafluorophosphate (bmimPF 6 ) and hydrochloride acid (HCl)/ammonium persulphate (APS) as the dopant/oxidant system [15]. Similar approach was employed by Haldorai et al [26] for the synthesis of poly(aniline-co-p-phenylene diamine) assisted by microwave radiation, obtaining nanorod structures. All these examples employ ILs as solvent.…”
Section: Introductionmentioning
confidence: 99%
“…[30][31][32][33][34][35] A report by Zhang and coworkers utilized imidazolium ILs as solvents for the phosphine-free Suzuki-coupling to give biaryls (with added water to improve reactivity). 29 Thiophene, 36,37 pyrrole 37 and aniline [38][39][40] have been polymerized by oxidative or electrochemical methods in ILs, typically giving insoluble lms or brils. To our knowledge, there is no prior report on Suzuki polymerization in an IL medium.…”
Section: Introductionmentioning
confidence: 99%