The In2O3 nanoparticles were homogeneously
attached on the BiOBr nanoplate surface to obtain S-scheme In2O3/BiOBr heterojunction photocatalysts by a hydrothermal
route. The purity, crystal structure, chemical state, morphology,
light absorption property, and photogenerated charge behavior of composites
were investigated by XRD, SEM, TEM, HRTEM, XPS, UV–vis DRS,
PL, ESR, and electrochemical tests. The removal of dyes (acid orange
7 (AO7), acid orange 10 (AO10), and rhodamine B (RhB)) and Cr(VI)
was employed to evaluate the photocatalytic performance of In2O3/BiOBr composites irradiated by simulated sunlight.
The results indicate that the photocatalytic performance of BiOBr
can be remarkably promoted after the decoration of In2O3 nanoparticles, and the best photocatalytic activity was achieved
over an 8% In2O3/BiOBr sample. The 8% In2O3/BiOBr sample also indicates outstanding synergistic
photocatalytic performance for the removal of the heavy metal ion/dye
mixture (AO7/Cr(VI) and RhB/Cr(VI)). It is found that the decoration
of In2O3 nanoparticles can accelerate the transfer
and separation of photoinduced electrons and holes in BiOBr nanoplates.
The energy band structure, work function, and Fermi level of BiOBr
and In2O3 were computed through the density
functional theory calculation. Based on the above investigation, the
photocatalytic mechanism of the S-scheme In2O3/BiOBr composite was discussed.