Dielectric ceramics in the Li 2 ZnTi 3 O 8 system were synthesized using TiO 2 nanoparticle reagent by the reaction-sintering process. The special effects of the TiO 2 nanoparticle reagent on the densification, phase distribution, microstructure, and dielectric properties were characterized using powder x-ray diffraction (XRD) analysis and scanning electron microscopy (SEM). A single phase of Li 2 ZnTi 3 O 8 ceramic was confirmed by the XRD pattern at all temperatures except 1075°C. The reaction between the starting materials was accelerated using TiO 2 nanoparticles, with pure Li 2 ZnTi 3 O 8 phase being created even at low sintering temperature of 900°C, along with increasing green specimen density at the compaction stage. The presence of TiO 2 phase in the Li 2 ZnTi 3 O 8 ceramic improved the s f value and shifted it to near zero at 1075°C, and the ceramic exhibited excellent microwave dielectric properties of e r = 23.5, Q Â f = 71,000 GHz, and s f = À3.5 ppm/°C.