The use of the microwave cavity in the study of ionization in shock waves in reactive gas mixtures is discussed. Some of the factors affecting the performance of a TE011 mode cavity are considered, and it is noted that the presence of end-holes in the cavity and a containing tube for the plasma both lead to a considerable enhancement of the cavity sensitivity. In the light of this, some results for the recombination rate constant of the oxyacetylene reaction diluted in argon obtained in a previous study are reanalysed and found to be in reasonable accord with those of other workers, obtained with a microwave interferometer.