The interference of different electromagnetic waves is considered a major concern in the current era. Various materials serve as potential candidates for shielding, but polymer composites have gained attention due to their superior properties. Polymer composites of poly(styrene-isoprene-styrene) (SIS) and polyaniline (PANI) are prepared with the help of solvent casting technique to study electromagnetic interference shielding effectiveness. To study the properties of these blends, different techniques were utilized, including FTIR, SEM, XRD. With the help of a conductivity test, the composites have shown improvement in electrical conductivity up to 1.18 Scm À 1 . Electromagnetic interference shielding effectiveness was measured within the X-band by using a vector network analyzer (VNA). The results observed showed an increase in attenuation up to 16dB upon optimum polyaniline concentration. The interaction and dispersion rate of filler is regarded as the primary aspect for enhanced properties. However, the agglomeration caused due to higher content of polyaniline resulted in decreased properties, i. e., 20 wt. % polyaniline.