“…The titania-bearing slags are by-products of the reduction smelting of vanadium titano-magnetite ore, producing 10 wt.% -28 wt.% TiO2 [5] from blast furnace smelting or 40 wt.% -70 wt.% TiO2 [6] from electric furnace smelting. In order to efficiently recover Ti values in the slag, different hydrometallurgical processes, including sulfuric acid leaching [7] , alkaline roasting-leaching [8] and various pyrometallurgical processes including microwave assistant roasting [9] , supergravity separation [10] , and selective crystallization -separation [11] , have been proposed. In the pyrometallurgical processes, the key idea is to enhance the Ti element concentration in a titania-enriched phase by modifying the slag composition [12] .…”