Abstract. Migmatites in the Quetico Metasedimentary Belt contain two types of leucosome:(1) Layer-parallel leucosomes that grew during deformation and prograde metamorphism. These are enriched in Si02, Sr, and Eu, but depleted in Ti02, Fe203, MgO, Cs, Rb, REE, Sc, Th. Zr, and Hf relative to the Quetico metasediments. (2) Discordant leucosomes that formed after the regional folding events when metamorphic temperatures were at their peak. These are enriched in Rb, Ba, Sr and Eu, but display a wide range of LREE, Th. Zr, and Hf contents relative to the Quetico metasediments.Layer-parallel leucosomes formed by a subsolidus process termed tectonic segregation. This stress-induced mass transfer pFocess began when the Quetico sediments were deformed during burial, and continued whilst the rocks were both stressed and heterogeneous. Subsolidus leucosome compositions are consistent with the mobilization of quartz and feldspar from the host rocks by pressure solution. The discordant leucosomes formed by partial melting of the Quetico metasediments, possibly during uplift of the belt. The range of composition displayed by the anatectic leucosomes arises from crystal fractionation during leucosome emplacement. Some anatectic leucosomes preserve primary melt compositions and have smooth REE patterns, but those with negative Eu anomalies represent fractionated melts, and others with positive Eu anomalies represent accumulations of feldspar plus trapped melt.