2011
DOI: 10.1080/19440049.2011.603705
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Migration of silver from nanosilver–polyethylene composite packaging into food simulants

Abstract: An analytical method for the determination of silver in food simulants (3% (w/v) aqueous acetic acid or 95% (v/v) aqueous ethanol) was developed based on inductively coupled plasma mass spectrometry (ICP-MS). Recoveries ranged from 87% to 109% and RSDs ranged from 0.7% to 7.8%. The procedure was applied to determine the migration of silver from nanosilver-polyethylene food packaging film into food simulants at different temperatures and migration times. Results indicated that the maximum migration ratios were … Show more

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Cited by 55 publications
(66 citation statements)
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“…The fraction of nanoparticulate Ag in relation to the total migrated Ag ranged from below 1% to 69% (Echegoyen & Nerín 2013;von Goetz et al 2013;Ramos et al 2016). Several studies on AgNP-containing polymers did not examine if the observed migration of Ag was due to migration of AgNPs (e.g., Busolo et al 2010;Emamifar et al 2010;Song et al 2011;Bott et al 2014b;Jokar & Abdul Rahman 2014). Only one experimental study that applied a method to detect ENOs (transmission electron microscopy -TEM) described the absence of AgNPs in migrates from AgNP-containing polymer (Ntim et al 2015).…”
Section: Open Question 1: Can Enos Migrate From Fcms At All?mentioning
confidence: 99%
See 1 more Smart Citation
“…The fraction of nanoparticulate Ag in relation to the total migrated Ag ranged from below 1% to 69% (Echegoyen & Nerín 2013;von Goetz et al 2013;Ramos et al 2016). Several studies on AgNP-containing polymers did not examine if the observed migration of Ag was due to migration of AgNPs (e.g., Busolo et al 2010;Emamifar et al 2010;Song et al 2011;Bott et al 2014b;Jokar & Abdul Rahman 2014). Only one experimental study that applied a method to detect ENOs (transmission electron microscopy -TEM) described the absence of AgNPs in migrates from AgNP-containing polymer (Ntim et al 2015).…”
Section: Open Question 1: Can Enos Migrate From Fcms At All?mentioning
confidence: 99%
“…The large body of literature evidenced dissolution of metal-containing nanoparticles, like Ag (Table 1) and zinc oxide nanoparticles, into ions from FCMs into food/food simulants (Kumar et al 2005;Song et al 2011;Jokar & Abdul Rahman 2014;Ntim et al 2015). Dissolution rate depends on redox potential and surface functionalisation of the ENO as well as ionic strength, temperature and dissolved oxygen level of the surrounding medium.…”
Section: Open Question 2: If Migration Of Enos Occurs What Is the MImentioning
confidence: 99%
“…Song et al (2011) described the migration of ionic silver from polyethylene nanocomposite; migration of silver nanoparticles (seen by SEM-EDX) was found by Huang et al (2011) from polyethylene plastic bags and Echegoyen and Nerín (2013) from both polypropylene food containers and polyethylene plastic bags. The amount of silver migration in those studies was found to be higher in acidic simulants, by increasing temperature and time of contact and by microwave heating compared to a regular oven.…”
Section: Migration Of Nanomaterials From Food Packagingmentioning
confidence: 97%
“…(87) Several atomic spectrometry techniques such as flame atomic absorption spectrometry (FAAS) and electrothermal atomic absorption spectrometry (ETAAS), inductively coupled plasma-atomic emission spectroscopy (ICP-AES), and ICP-MS have been proposed for the determination of the chemical composition of inorganic nanoparticles. (85,88,89) Separation techniques are used to isolate nanoparticles and to determine their size and size distribution. The best known technique for size separation is size exclusion chromatography (SEC).…”
Section: Determination Of Nanomaterials In Foodmentioning
confidence: 99%