The influence of the temperature and its duration, that are among the most important components to determine the fire effects on soil properties, were studied in the 0-5 cm layer of a Humic Cambisol developed over siliceous conglomerates and under a shrub of Erica australis. Soil was sandy loam with 8.5 g 100 g − 1 of organic matter, pH of 4.7 and available P about 0.16 mg kg − 1 . The water stability index (WSI) was 64.9, which was considered good. Differential thermal analysis (DTA) showed the presence of two peaks, one endothermic until 177°C and other exothermic between 229°C and 579°C. Samples were heated at 100°C, 200°C and 500°C during 5, 15, 30 and 60 min after reaching the selected temperature. To avoid a temperature gradient in the profile a sample layer of 2 cm depth was used. Soil heating to 100°C at the four heating times and to 200°C for 5 min did not produce significant changes in pH, organic matter, total N, C/N ratio, available P, extractable cations and WSI. Soils heated to 200°C for 15, 30 and 60 min and 500°C for 5 min, showed a significant increase in available P (from 0.9 to a maximum of 17.6 mg kg −1 ) and divalent cations (Ca 2+ from 4.4 to 46.3 and Mg 2+ from 1.5 to 8.7 mg kg − 1 ). For soils heated to 500°C for 15, 30 and 60 min, a clear increase in soluble Na + content (from 0.5 to 1.8 mg kg −1 ) and pH (from 5.5 to 8.1), in addition to a significant decrease in organic matter (from 8.7% to 2.4%) was detected. As a consequence an important decrease in WSI was found (from 64.9% to 54.3%).