Mineralogical and Technological Characterization of Zeolites from Basin and Range as Pozzolanic Addition of Cement

Montesano, Giovanna; Cappelletti, Piergiulio; Caputo, Domenico; Liguori, Barbara; Campanile, Assunta; Rispoli, Concetta

doi:10.3390/ma15072684

Cited by 6 publications

(4 citation statements)

References 36 publications

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“…In addition, after alginate coating, calcium deposition increased in both 7 and 14 days. Similarly, various studies [68][69][70][71][72][73][74][75][76][77][78][79][80] reported that alginate coating increased calcium deposition and new bone formation. For example, Jang et al [69] demonstrated the great calcium deposition results on the PCL scaffold with alginate coating.…”

Section: In Vitro Cytocompatibility Of Scaffoldsmentioning

confidence: 91%

Antibacterial Activity and Cell Responses of Vancomycin-Loaded Alginate Coating on ZSM-5 Scaffold for Bone Tissue Engineering Applications

et al. 2022

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Despite the significant advancement in bone tissue engineering, it is still challenging to find a desired scaffold with suitable mechanical and biological properties, efficient bone formation in the defect area, and antibacterial resistivity. In this study, the zeolite (ZSM-5) scaffold was developed using the space holder method, and a novel vancomycin-loaded alginate coating was developed on it to promote their characteristics. Our results demonstrated the importance of alginate coating on the microstructure, mechanical, and cellular properties of the ZSM-5 scaffold. For instance, a three-fold increase in the compressive strength of coated scaffolds was observed compared to the uncoated ZSM-5. After the incorporation of vancomycin into the alginate coating, the scaffold revealed significant antibacterial activity against Staphylococcus aureus (S. aureus). The inhibition zone increased to 35 mm. Resets also demonstrated 74 ± 2.5% porosity, 4.3 ± 0.07 MPa strength in compressive conditions, acceptable cellular properties (72.3 ± 0.2 (%control) cell viability) after 7 days, good cell attachment, and calcium deposition. Overall, the results revealed that this scaffold could be a great candidate for bone tissue engineering.

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Section: In Vitro Cytocompatibility Of Scaffoldsmentioning

confidence: 91%

Antibacterial Activity and Cell Responses of Vancomycin-Loaded Alginate Coating on ZSM-5 Scaffold for Bone Tissue Engineering Applications

et al. 2022

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“…Costafreda et al [20] and Costafreda [21] detailed in their previous research the pozzolanic characteristics of the zeolite of the Loma Blanca deposit, which were demonstrated once again in this work. Works such as those of Montesano et al [22], Uhlík et al [23], and Mertensa et al [24] established well the pozzolanic reactivity of zeolitised tuffs consisting mainly of mordenite and clinoptilolite.…”

Section: Chemical Analysis Of Pozzolanicity (Pt) At 8 and 15 Daysmentioning

confidence: 98%

A New Study on the Eastern Flank of the Loma Blanca Deposit (Cuba) to Establish the Mineralogical, Chemical, and Pozzolanic Properties of Zeolitised Tuffs

et al. 2022

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The geological nature of the territory of the Republic of Cuba has favoured the formation of large and varied deposits of volcanic tuffs enriched by various species of zeolites. Today, new zeolite deposits continue to be discovered in the country. This work aims to present the results of a study carried out in an unexplored area that is located approximately 1.2 km east of the Loma Blanca deposit, outside the mining operation limits. To carry out this research and to establish a qualitative comparison between both sample populations, four samples were taken from the study area, and another four were taken from the Loma Blanca deposit. The characterisation of the samples was performed by XRD, SEM, and XRF. The pozzolan quality was determined by the pozzolanicity test (PT) and quality chemical analysis (QCA). Finally, a study of the mechanical strength (MST) was performed at 7, 28, and 90 days, using mortar specimens made with PC/ZT: 75–25% and PC/ZT: 70–30%, respectively. The results of the studies using XRD, SEM, and XRF indicated that both groups of samples had a similar complex mineralogical composition, consisting mainly of mordenite and clinoptilolite accompanied by secondary phases such as quartz and amorphous materials in the form of altered glass. The pozzolanicity test showed that both the samples from the study area and those from the Loma Blanca deposit behaved like typical pozzolans, which is a trend that can be seen in the high values of mechanical strength to compression up to 72 MPa for the PC/ZT: 75–25% formulation and 66 MPa for the PC/ZT: 70–30%. The results obtained establish that the zeolite varieties detected in the study area are similar to those of the Loma Blanca deposit, which could have a positive impact on the increase in current reserves, especially for manufacturing pozzolanic cements with properties that contribute to the preservation of the environment.

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“…According to [28], the first activity phases of the continental Phlegraean Fields correspond to Punta Marmolite and Cuma lava domes (~47 and ~37 ka, respectively), Torre Franco Tuff Formation (~42 ka) and San Martino lava dome (~77 ka). The two main eruptive events date back to ~39 ka ( 40 Ar/ 39 Ar; [28,29] and ~15 ka ( 40 Ar/ 39 Ar; [3]). The former is represented by the Campanian Ignimbrite eruption, the most catastrophic explosive event of the Mediterranean area in the last 200 ka, the latter is represented by the eruption of Neapolitan Yellow Tuff, the most impressive event of the Phlegraean Fields in terms of thickness and areal distribution [30].…”

Section: Geological Backgroundmentioning

confidence: 99%

“…These geomaterials are particularly interesting due to their great use in the Roman age. Roman craftsmen used to combine lime and pozzolana, (formerly Pulvis Puteolana, volcanic sand from Pozzuoli, Italy) related to Neapolitan Yellow Tuff (NYT-15 ka) formation [2,3].…”

Section: Introductionmentioning

confidence: 99%

Ancient Roman Mortars from Anfiteatro Flavio (Pozzuoli, Southern Italy): A Mineralogical, Petrographic and Chemical Study

et al. 2022

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This research is based on the characterization of ancient mortars from the Anfiteatro Flavio (Pozzuoli) dating back to the 1st and 2nd century CE through a multi-analytical approach involving macroscopic, mineralogical, petrographic, and chemical investigations. The goal that has been set is to deepen knowledge about mortar mix design, the provenance of used raw materials, and secondary minerogenetic processes that have occurred within ancient Roman mortars. Results show that: (i) raw materials for mortar preparation have a local provenance, i.e., Phlegraean Fields area; (ii) mortars can be considered as hydraulic; (iii) calcite presence could be due to a non-complete calcination process, an improper slaking or to exposition of materials to the subaerial environment; (iv) gypsum is due to calcite sulfation process; (v) halite presence is due to marine aerosol exposition. The achieved information testifies that, for at least two centuries, Roman builders considered the identified mortar mix as optimal for their buildings, but also contributes to the understanding of their technical skills and represents an important first step to planning future restoration operations.

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Mineralogical and Technological Characterization of Zeolites from Basin and Range as Pozzolanic Addition of Cement

Cited by 6 publications

References 36 publications

Antibacterial Activity and Cell Responses of Vancomycin-Loaded Alginate Coating on ZSM-5 Scaffold for Bone Tissue Engineering Applications

Antibacterial Activity and Cell Responses of Vancomycin-Loaded Alginate Coating on ZSM-5 Scaffold for Bone Tissue Engineering Applications

A New Study on the Eastern Flank of the Loma Blanca Deposit (Cuba) to Establish the Mineralogical, Chemical, and Pozzolanic Properties of Zeolitised Tuffs

Ancient Roman Mortars from Anfiteatro Flavio (Pozzuoli, Southern Italy): A Mineralogical, Petrographic and Chemical Study

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