“…This spectroscopy provides useful information on the qualitative and quantitative occurrences of Fe-bearing minerals and amorphous phases in coal. ,,,,,− The Fe 2+ /Fe 3+ ratio, crystal data peculiarities, and solid solutions in Fe-containing coal minerals and phases can also be characterized. For example, these data can be used for a detection of the oxidation and weathering levels of Fe sulfides to Fe 2+ and Fe 3+ sulfates, and later to Fe oxyhydroxides. ,,− Transformations of Fe minerals following other treatments have been studied as well. ,,− The MS has also been proposed as an alternative to wet chemical methods for pyrite analysis in coal. ,,− The application and perspectives of this technique for coal characterization have been recently reviewed …”