Minerály kontaminovaných granitových pegmatitů z lomu Pohled u Havlíčkova Brodu (moldanubikum), část II: prvky a sulfidy

Abstract

In the Pohled quarry near Havlíčkův Brod town (central part of Czech Republic), texturally and mineralogically simple contaminated anatectic pegmatites form dikes or irregular bodies cementing breccia of host metamorphic rocks (paragneisses, amphibolites) belonging to the Monotonous (Ostrong) Group of the Moldanubicum of the Bohemian Massif. They exhibit signs of intense hydrothermal overprint and also the presence of abundant disseminations, nests and veinlets of ore minerals. A detailed mineralogical study revealed the presence of an extraordinary rich ore assemblage (20 species in total, including one unnamed phase). The oldest minerals are sphalerite (rich in Fe), löllingite, Fe-Co-Ni sulphoarsenides (cobaltite, glaucodot, arsenopyrite, gersdorffite), pyrrhotite, galena and chalcopyrite, in later portion accompanied by inclusions of Bi-minerals (native bismuth, bismuthinite, joséite-A, joséite-B, ikunolite and a Pb-Bi sulphosalt). The composition of the Pb-Bi sulphosalt is equal to Ag,Fe-substituted eclarite; its identity was confirmed also by Raman spectrum. Pyrite is very abundant phase, present probably in several generations. The Fe-Co-Ni thiospinels disseminated in younger chlorite, and represented by siegenite, violarite, grimmite and an unnamed NiFe2S4 phase, are the youngest ore minerals. The mineral association as well as chemical composition of most ore minerals are well comparable to those of local polymetallic ore veins and Alpine-type veins, which give evidence for identical origin of all these ore mineralizations. The formation of pegmatite-hosted ore assemblage was long-lasting multiphase process, which took place at temperatures between ca. 350 and <120 °C during changing fugacities of sulphur, tellurium and oxygen. A distinct enrichment in cobalt and nickel of ore mineralization hosted by pegmatites (in comparison with hydrothermal veins) is explained in terms of pronounced interactions of fluids with amphibolites and serpentinites.

Mineralogy and Origin of Vein Wolframite Mineralization from the Pohled Quarry, Havlíčkův Brod Ore District, Czech Republic: Interaction of Magmatic and Basinal Fluids

“…Both the mineralogical and the geochemical features suggest that the Pohled granite is just between S-and I-type granite. Metamorphites are frequently cut by dykes and irregular bodies of rather primitive granitic pegmatites with signs of intense superimposed hydrothermal alteration associated with the introduction of sulfur and ore metals [29,30]. In addition, both the granite and the metamorphites are cut by several types of hydrothermal veins.…”

“…The boundary between monoclinic and hexagonal pyrrhotite is adopted from [62]. The comparative data are from [30,35,36,40]. The boundary between monoclinic and hexagonal pyrrhotite is adopted from [62].…”

“…The boundary between monoclinic and hexagonal pyrrhotite is adopted from [62]. The comparative data are from [30,35,36,40].…”

“…[64] and [65], the unnamed phases are marked by appropriate formulae. Comparative data are from [30].…”

Wolframová a sulfidická hydrotermální mineralizace z Pekelského vrchu u Jihlavy (Česká republika)

“…V nábrusech křemenné žiloviny tvoří nepravidelné agregáty o rozměrech do 1 mm nebo výplně trhlin v křemeni, případně jehličkovité agregáty až 0.1 mm velké. 1983;Scott 1987;Rattray et al 1996;Jambor 1999;Kolitsch, Pring 2001;Sejkora et al 2001;Mills et al 2008;Sejkora et al 2009;Bayliss et al 2010;Vrtiška et al 2019;Sejkora et al 2021). Příklady složení fází z Pekelského vrchu jsou spolu s jejich koeficienty empirických vzorců uvedeny v tabulce 18.…”