Miniaturization of spectrophotometry based on micro flow analysis using norfloxacin as less-toxic reagent for iron determination

Prasertboonyai, Kanyarak; Arqueropanyo, Orn-anong; Liawraungrath, B.; Liawraungrath, Saisunee; Pojanakaroon, Teraboon

doi:10.1016/j.saa.2015.07.017

Cited by 13 publications

(9 citation statements)

References 29 publications

Supporting

Mentioning

Contrasting

Unclassified

Order By: Relevance

“…Additionally, the linear range response of these methods is quite narrow, so large dilutions must be made when analyzing high concentration samples, which is often a source of error for Fe(III) concentration. The linear range found in similar works is 0.05–4.0 mg·L −1 [ 32 ], 1–40 mg·L −1 [ 29 ], 0.2–5 mg·L −1 [ 33 ], 0.021–2.4 mg·L −1 [ 34 ], 40–350 mg·L −1 [ 35 ] and 110–560 mg·L −1 [ 36 ].…”

Section: Introductionmentioning

confidence: 69%

Microflow injection analysis based on modular 3D platforms and colorimetric detection for Fe(III) monitoring in a wide concentration range

Ricart,

Dorado,

Lao-Luque

et al. 2023

Microchim Acta

View full text Add to dashboard Cite

A modular microflow injection analysis (microFIA) system for the determination of Fe(III) in a bioleaching reactor has been designed, developed and validated. The different modules of the analyzer (mixer, diluter, disperser and detector) were 3D-printed. Fe(III) quantification is due by measuring the color intensity of the chelate formed between Fe(III) and salicylic acid at 525 nm. The device has been designed to dilute, disperse and detect high Fe(III) concentrations in the form of an inexpensive multi-step photometric flow cell that uses an light-emitting diode (LED) as a light source and an light-dependent resistor (LDR) as a light intensity detector. This microFIA system has been shown to be suitable for automatic and continuous determination of Fe(III) in the operation of a bioreactor for the oxidation of Fe(II). The device has a good repeatability (less than 5% of coefficient of variation in the whole range of concentrations) and accuracy of around 100%. The analyzer features an exceptional wide linear range, between 25 and 6000 mg·L−1. The device was successfully applied to the determination of Fe(III) in real samples. The obtained results proved that the method is applicable for accurate, precise, rapid, and low-cost colorimetric analysis and didn’t show significant differences with a conventional UV–Vis method. Graphical Abstract

show abstract

Section: Introductionmentioning

confidence: 69%

Microflow injection analysis based on modular 3D platforms and colorimetric detection for Fe(III) monitoring in a wide concentration range

Ricart,

Dorado,

Lao-Luque

et al. 2023

Microchim Acta

View full text Add to dashboard Cite

show abstract

“…Pada kadar 1-2 ppm besi dapat menyebabkan air berwarna kuning, terasa pahit, meninggalkan noda pada pakaian dan porselin [1]. Beberapa teknik spektrofotometri dalam analisis besi antara lain spektrofotometri serapan atom (AAS), spektrometri massa induksi plasma (ICP-MS), spektrofluorometri [2], dan spektrofotometri UV-Vis.…”

Section: Pendahuluanunclassified

Analisis Perbandingan Pengaruh Campuran ION Cu2+ dan Ni2+ Pada Penentuan Kadar Fe Sebagai Fe(II)-Fenantrolin

Budianti

Suprapto

2017

JSSITS

View full text Add to dashboard Cite

Abstrak-Analisis besi(II) dengan pengompleks 1,10-fenantrolin pada pH 4,5 yang diganggu dengan penambahan campuran ion Cu 2+ dan Ni 2+ menggunakan spektrofotometer UV-Vis telah berhasil dipelajari. Pada penentuan panjang gelombang maksimum kompleks Fe(II)-fenantrolin diperoleh panjang gelombang maksimum sebesar 510 nm. Sedangkan kompleks Cu(II)-fenantrolin menyerap sinar pada panjang gelombang maksimum 315 nm dan kompleks Ni(II)-fenantrolin pada panjang gelombang maksimum 330 nm. Pada penentuan kurva kalibrasi diperoleh persamaan regresi linear yaitu y = 0,1248x + 0,013 dengan nilai koefisien korelasi (r) adalah 0,9990 dan koefisien determinasi (r 2) adalah 0,9982. Penambahan campuran ion Cu 2+ dan Ni 2+ mengakibatkan adanya kenaikan nilai absorbansi pada kompleks Fe(II)-fenantrolin. Campuran ion Cu 2+ dan Ni 2+ mulai mengganggu pada konsentrasi Cu 2+ 0,4 ppm dan konsentrasi Ni 2+ 0,6 ppm. Nilai % recovery pada variasi konsentrasi Cu 2+ dan Ni 2+ yaitu 120,4594 %, standar deviasi (RSD) sebesar 0,7550 ppt, dan koevisie n variasi (CV) sebesar 0,0755%.

show abstract

“…Te natural deposits and refning of iron ores and industrial wastes are essential parameters for the existence of iron in natural water such as rivers, lakes, and groundwater. Te iron level in groundwater can be increased by the dissolution of iron compounds in soils or ferrous boreholes and handpump components through leaching from home water drinking, cooking, washing, cleaning, and agricultural purposes [1,2]. Generally, iron exists in natural fresh waters in the range of 0.5 to 50 mg L −1 .…”

Section: Introductionmentioning

confidence: 99%

An Environmentally Friendly Compact Microfluidic Hydrodynamic Sequential Injection System Using Curcuma putii Maknoi & Jenjitt. Extract as a Natural Reagent for Colorimetric Determination of Total Iron in Water Samples

Namjan

Kaewwonglom

Theerakarunwong

et al. 2023

Journal of Analytical Methods in Chemistry

View full text Add to dashboard Cite

The miniaturization of analytical systems and the utilization of nontoxic natural extract from plants play significant roles for green analytical chemistry methodology. In this work, the microfluidic hydrodynamic sequential injection (HSI) with the LED-phototransistor colorimetric detection system has been proposed to create an ecofriendly and low-cost miniaturized analytical system for online determination of iron in water samples using Curcuma putii Maknoi & Jenjitt. extracts as high stability and good selectivity of a natural reagent. The proposed method was designed for online solution mixing and colorimetric detection on a microfluidic platform. The Curcuma putii Maknoi & Jenjitt. extracts and standard/samples were sequentially aspirated to fill the channel before entering the built-in flow cell. The intensity of iron-Curcuma putii Maknoi & Jenjitt. extract complex was monitored under the optimum conditions of flow rate, sample volume, mixing zone length, and aspiration sequences, by altering the gain control of the colorimetric detector to achieve good sensitivity. The results demonstrated a good performance of the green analytical systems. A linear calibration graph in the range of 0.5–6.0 mg L−1 was obtained with a limit of detection at an adequate level of 0.11 mg L−1 for water samples with a sample throughput of 30 h−1. The precise and accurate measurement results were achieved with relative standard deviations in the range of 1.61–1.72%, and percent recoveries were found in the range of 90.6–113.4. The proposed method offers cost-effective, easy operation over an appropriate analysis time (2 min/injection) with good sensitivity and is environmentally friendly with low consumption of solutions and the use of high stability and good selectivity of nontoxic reagents. The achieved method was demonstrated to be a good choice for routine analysis.

show abstract

Miniaturization of spectrophotometry based on micro flow analysis using norfloxacin as less-toxic reagent for iron determination

Cited by 13 publications

References 29 publications

Microflow injection analysis based on modular 3D platforms and colorimetric detection for Fe(III) monitoring in a wide concentration range

Microflow injection analysis based on modular 3D platforms and colorimetric detection for Fe(III) monitoring in a wide concentration range

Analisis Perbandingan Pengaruh Campuran ION Cu2+ dan Ni2+ Pada Penentuan Kadar Fe Sebagai Fe(II)-Fenantrolin

An Environmentally Friendly Compact Microfluidic Hydrodynamic Sequential Injection System Using Curcuma putii Maknoi & Jenjitt. Extract as a Natural Reagent for Colorimetric Determination of Total Iron in Water Samples

Contact Info

Product

Resources

About