“…Such dilute nitride III-V compounds have attracted attention in recent years due to realised device applications, including subcells in world record efficiency multi-junction solar cells, as in the case of GaInNAsSb, 1 and potential applications such as light sources and photodetectors in the long-wavelength infrared range. [2][3][4] The property of band gap reduction upon N incorporation has already been observed in GaNAs, 5 GaNP, 6 GaInNAs, 7 InNAs, 8 and GaNSb. 9,10 It has been described in terms of conduction band anticrossing (BAC), wherein a localized nitrogen level interacts with the extended host conduction band.…”