When an input terminal is connected to a solar panel with a low voltage level and large power range fluctuation, a Boost type CLLC converter controlled by fixed frequency pulse width modulation (PWM) reduces the utilization of PV electric energy, and the synchronous drive of the secondary side and primary side ensures that the converter operates with low efficiency when the duty cycle is shifted by 0.5. To maximize the utilization of photovoltaic (PV) energy in a PV power generation system and improve the conversion efficiency, this paper studies a Boost CLLC converter with high gain and soft switching controlled by PWM-pulse frequency modulation (PFM) hybrid modulation for PV power generation. By controlling the duty cycle and switching frequency of the primary MOSFETs, the converter can stabilize the output voltage while tracking the PV maximum power point. Under such a hybrid control, the resonant gain of the converter is greater than 1, the voltage gain is large, one of the MOSFETs at the primary side is in a zero-voltage-switching-open (ZVS-ON) state, two diodes are used to realize zerocurrent-switching (ZCS) soft switching on the secondary side, and the efficiency of the converter is high. In addition, this paper studies the phenomenon of backflow power in the resonant circuit and the influence of a change in the switching frequency on the magnitude of the backflow power. Finally, a 500W experimental prototype was constructed to verify the accuracy of the theoretical analysis and the feasibility of the control method.