Imbibition, the process of a wetting fluid displacing a nonwetting one in porous media, occurs in many natural and industrial processes, such as enhanced oil recovery and geological carbon sequestration. The phenomenon of imbibition shifts from the capillary regime to the capillary–viscous regime as the externally imposed flow rate (viscous force) increases. In the capillary–viscous regime, there also exists a transition from the capillary-dominated regime to viscous-dominated regime, and the identification of this transition is fundamental to the description of forced imbibition. The main purpose of this work is to explore regime transition in imbibition. We first investigate forced imbibition in a heterogeneous porous media over a broad range of wettability conditions and flow rates. An energy capillary number is proposed to identify regime transitions based on the energy balance analysis of imbibition processes, especially the transition from a capillary-dominated regime to viscous-dominated regime. The energy capillary number is defined as the ratio of the reduced surface energy to the external work, measuring the relative total contribution of the capillary force vs the viscous force to the whole imbibition morphologies. We further present a phase diagram, which allows us to determine the imbibition regime directly from capillary numbers and wettability conditions. The energy capillary number and phase diagram are evidenced by a quantitative analysis of invasion morphologies.