Halide perovskites have been known to be photoconductive for more than half a century, and their efficient photocarrier generation gives rise to positive photoconductivity (PPC). In this work, we report the discovery of negative photoconductivity (NPC) in hybrid perovskite CH 3 NH 3 PbBr 3 after Bi doping. Transient photoconductivity measurements reveal a surprising bipolar behavior with a fast positive response followed by exponential negative photocurrent decay, resulting in an equilibrium photocurrent even below the dark level. The NPC effect in Bidoped CH 3 NH 3 PbBr 3 is among the largest ones reported so far for semiconductors. We propose that the transition to negative photoconductance is related to the presence of DX-like centers in Bi-doped halide perovskites, similar to doped III-V and chalcopyrite semiconductors. Such photogenerated DX-like centers in the Bi-doped CH 3 NH 3 PbBr 3 can trap mobile band electrons