The ablation dynamics of a tin (Sn) micro-droplet by double pulse laser irradiation for the development of an extreme ultraviolet lithography source was investigated. The solid state Sn droplet target with a diameter of 30 µm was irradiated by double laser pulses from a Q-switched Nd : YAG laser and a CO2 laser, and the kinetic behaviour of debris such as Sn atoms, ions and of the dense particles from the droplet was investigated by the laser-induced fluorescence imaging method, Faraday cups and high-speed imaging, respectively. After the pre-pulse irradiation of the Nd : YAG laser, the ions were emitted towards the laser incident direction with an average kinetic energy of 3–6 keV and the dense particle cloud moved in the direction opposite to the laser incident direction with expansion by a reaction force due to the plasma expansion at a speed of approximately 500 m s−1. On the other hand, the Sn atoms were ejected in all directions from the target with a speed as fast as 20 km s−1. The expanding target was subsequently irradiated by the main pulse of the CO2 laser with a delay of 800 ns and the dense cloud almost disappeared due to main-pulse irradiation.