Mitigation of Mild Steel Corrosion in Acid by Green Inhibitors: Yeast, Pepper, Garlic, and Coffee

Paul, Subir; Kar, Bikash

doi:10.5402/2012/641386

Cited by 15 publications

(12 citation statements)

References 13 publications

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“…A few natural products such as plant extracts and animal proteins were reported [9] to have been used in pickling acid bath. In the previous investigation by the author [10], corrosion inhibition of carbon steel by few green inhibitors viz. garlic, yeast, pepper, and coffee is studied.…”

Section: Introductionmentioning

confidence: 98%

Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor

Paul

Koley

2016

J Bio Tribo Corros

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Chemicals used presently for corrosion inhibitors in Industries are highly toxic to both human beings and environment. These inhibitors may cause the damage to organ system viz., kidneys or liver, or to disturb a biochemical process of an enzyme system at some site in the body. For papaya seed, a vegetable waste is found to act as a very good green inhibitor, in preventing acid corrosion of low-carbon construction steel. The study was made in 0.5 to 3 N H 2 SO 4 with the variation of concentration. An increase in inhibitor concentration decreases the rate of degradation. But there is an optimum concentration at which the inhibitor effect is maximum, beyond that the corrosion rate again increases. The adsorption study shows that the mechanism of corrosion inhibitor is due to physical adsorption, following Temkin adsorption isotherms. Electrochemical impedance spectroscopy study showed that the corrosion inhibition by the papaya seed is due to an increase in polarization resistance and impedance at metalsolution interface.

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Section: Introductionmentioning

confidence: 98%

Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor

Paul

Koley

2016

J Bio Tribo Corros

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“…The Frumkin isotherm 26,27 assumes unit coverage at high inhibitor concentrations and that the electrode surface is inhomogeneous or that the lateral interaction effect is not negligible. In this way, only the active surface of the electrode, on which adsorption occurs, is taken into account.…”

Section: Adsorption Isothermsmentioning

confidence: 99%

Inhibition effect of deanol on mild steel corrosion in dilute sulphuric acid

Loto

Popoola

2015

S.Afr.j.chem

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The influence of deanol on the corrosion behaviour of mild steel in dilute sulphuric acid with sodium chloride addition was studied by means of mass-loss, potentiodynamic polarization, electrode potential monitoring, scanning electron microscopy and statistical analysis. Results show that deanol performed excellently with a maximum inhibition efficiency of 97.9 % obtained from the mass loss technique and 98.23 % from the potentiodynamic polarization tests at the maximum deanol concentration evaluated. Polarization studies show that the amino alcohol is a cathodic type inhibitor. Adsorption of deanol on the steel surface was observed to obey the Langmuir and Frumkin adsorption isotherms. Scanning electron microscopy studies confirmed the corrosion protection property of deanol to be through adsorption on the mild steel surface while statistical evaluation showed the overwhelming influence and significance of inhibitor concentration on inhibition efficiency compared with exposure time. KEYWORDSOrganic compounds, metals, deanol, corrosion, sulphuric acid, inhibitor IntroductionMild steel has excellent mechanical properties. Its low cost allows for extensive use as the material of construction in petroleum industries, chemical processing plants, marine applications, boilers, refinery plants, extractive industries, etc. However, its application under these industrial conditions subjects it to rapid corrosion attack especially in applications involving the extensive use of sulfuric acid and other corrosive media due to their wide range of applications, including domestic acidic drain cleaner, electrolyte in lead-acid batteries and various cleaning agents.1 The most cost-effective and practical corrosion control technique for effectively preventing the occurrence or reducing the severity of corrosion is to alter the electrochemical nature of the environment with chemical compounds known as inhibitors.2,3 Effective corrosion inhibition is subject to the chemical composition, molecular structure and affinity of the inhibiting compound with the metallic alloy surface. Deanol has been used for corrosion prevention in concrete with mixed results. [4][5][6][7] The compound adsorbs through concrete resulting in the formation of a complex precipitate of protective film, which adsorbs onto the metal surface. This provides an impenetrable barrier to metal dissolution that acts to stifle cathodic and or anodic electrochemical corrosion reactions taking place at the metal/solution interface. This investigation aims to evaluate the corrosion inhibition properties of deanol on the electrochemical behaviour of mild steel in aqueous dilute sulphuric acid at ambient temperature of 25 °C.

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“…The slopes of the isotherms show deviation from the value of unity. This deviation from unity may be due to the interaction among the adsorbed species on the metal surface; that is, the organic molecules having polar atoms or groups get adsorbed on the cathodic and anodic sites of the metal surface by replacing the initially adsorbed water molecule [27]. The standard free energy of adsorption (Δ ∘ ads ) is related to ads by the following relation [28]:…”

Section: Adsorption Isothermmentioning

confidence: 99%

Corrosion Inhibition Effect of 4-Hydroxy-N′-[(E)-(1H-indole-2-ylmethylidene)] Benzohydrazide on Mild Steel in Hydrochloric Acid Solution

Kumari

Shetty

Rao

2014

International Journal of Corrosion

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The inhibition performance and adsorption behaviour of 4-hydroxy-N′-[(E)-(1H-indole-2-ylmethylidene)] benzohydrazide (HIBH) on mild steel in 1 M HCl solution were tested by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). The inhibition efficiency of HIBH increases with increase in inhibitor concentration in the temperature range 30–60°C. Polarisation curves indicate that HIBH is a mixed inhibitor, affecting both cathodic and anodic corrosion currents. The adsorption process of HIBH at the mild steel/hydrochloric acid solution interface obeyed Langmuir adsorption isotherm model and inhibition takes place by mixed adsorption, predominantly chemisorption. The activation and thermodynamic parameters for the corrosion inhibition process were calculated to elaborate the mechanism of corrosion inhibition.

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Mitigation of Mild Steel Corrosion in Acid by Green Inhibitors: Yeast, Pepper, Garlic, and Coffee

Cited by 15 publications

References 13 publications

Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor

Corrosion Inhibition of Carbon Steel in Acidic Environment by Papaya Seed as Green Inhibitor

Inhibition effect of deanol on mild steel corrosion in dilute sulphuric acid

Corrosion Inhibition Effect of 4-Hydroxy-N′-[(E)-(1H-indole-2-ylmethylidene)] Benzohydrazide on Mild Steel in Hydrochloric Acid Solution

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