Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

Adonin, S. A.; Abramov, P. A.; Zaguzin, A. S.; Novikov, A. S.

doi:10.1134/s0022476624070126

J Struct Chem

2024

DOI: 10.1134/s0022476624070126

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Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

S. A. Adonin,

P. A. Abramov,

A. S. Zaguzin

et al.

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Halogen-Bonded Assemblies in Half-Sandwich Noble Metal Complexes with Bis(4-iodopyrazol-1-yl)methane: Structural and Computational Analyses

Pavlova,

Pavlov,

Fedin

et al. 2024

Crystal Growth & Design

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Four half-sandwich noble metal complexes containing bis(4-iodopyrazol-1-yl)methane ligand (bpmI), [M(p-cym)-(bpmI)Cl]Cl (M = Ru 2+ and Os 2+ ), and [M(bpmI)(Cp*)Cl]Cl (M = Rh 3+ and Ir 3+ ) were synthesized and characterized by singlecrystal X-ray diffraction analysis. C−I•••Cl halogen bonds between the iodine atoms of the bis(4-iodopyrazol-1-yl)methane and the Cl − anions were found to be the structure-defining contacts for all complexes. Bis(4-iodopyrazol-1-yl)methane acts as both the bidentate ligand and 180°-orienting halogen bond donor in these half-sandwich complexes, which further assemble into halogenbonded polymeric chains. The existence and noncovalent nature of these interactions were confirmed by the topological analysis of the electron density distribution with the help of the atoms in molecules (AIM) approach, followed by noncovalent interactions analysis of the reduced density gradient (RDG). The influence of the nature of the metal center and the presence of solvate molecules on the halogen bond strength was analyzed.

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Halogen-Bonded Assemblies in Half-Sandwich Noble Metal Complexes with Bis(4-iodopyrazol-1-yl)methane: Structural and Computational Analyses

Pavlova,

Pavlov,

Fedin

et al. 2024

Crystal Growth & Design

View full text Add to dashboard Cite

show abstract

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Mixed-Ligand Chloride Complex of Co(II) withE-2-(((4-Iodophenyl)Imino)Methyl)Phenol: Crystal Structure and Features of Halogen Bonding in a Solid

Cited by 1 publication

References 62 publications

Halogen-Bonded Assemblies in Half-Sandwich Noble Metal Complexes with Bis(4-iodopyrazol-1-yl)methane: Structural and Computational Analyses

Halogen-Bonded Assemblies in Half-Sandwich Noble Metal Complexes with Bis(4-iodopyrazol-1-yl)methane: Structural and Computational Analyses

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