The dynamic fracture behavior of layered architectures is experimentally studied. Specifically, crack penetration, trapping, and branching at an interface are examined. A newly introduced optical technique called Digital Gradient Sensing (DGS) that quantifies elasto-optic effects due to a non-uniform state of stress is extended to perform full-field measurements during the fracture event using ultrahigh-speed photography. By exploiting the richness of two simultaneously measured orthogonal stress gradient fields, a modified approach for extracting stress intensity factors (SIFs) is implemented for propagating crack-tips under mixed-mode conditions. The method is first calibrated using a quasi-static experiment complemented by finite element simulations before implementing it for studying dynamic mixed-mode fracture mechanics of layered configurations. The layered systems considered consist of two PMMA sheets bonded using an acrylic adhesive with the interface oriented normally to the initial crack propagation direction. Interfaces are characterized as 'strong' and 'weak' by their crack initiation toughness. The dynamic fracture of monolithic PMMA sheet is also studied in the same configuration for comparison. The crack growth and fracture parameter histories of propagating cracks are evaluated. The interface is shown to drastically perturb crack growth behavior resulting in higher dissipation of fracture energy by exciting crack trapping, branching, and mixed-mode growth mechanisms.