Initiators can accelerate the pyrolysis of hydrocarbon
fuels, thereby
reducing the required reaction temperature in the hypersonic vehicle
heat exchanger/reactor. Nitro-alkanes are considered as efficient
initiators due to their lower energy barrier of the C–N bond
cleavage reaction. To research the mechanism of the initiation effect
of nitro-alkanes on the decomposition of hydrocarbon fuel, synchrotron
radiation vacuum ultraviolet photoionization-mass spectrometry (SVUV-PIMS)
was employed to experimentally study the pyrolysis of n-C10H22, 1-C3H7NO2, and their binary mixtures in a flow tube under pressures
of 30 and 760 Torr. The species identified and measured in the experiments
included alkanes, alkenes, dialkenes, alkynes, nitrogen oxides, benzene,
and free radicals, which revealed the mechanism of n-decane and 1-C3H7NO2 pyrolysis,
as well as the interactions of the two fuels. Experiments show that
the presence of 1-C3H7NO2 reduces
the initial decomposition temperature of n-C10H22, and the increased pressures could achieve
a stronger promoting effect on the conversion of n-C10H22. A detailed kinetic model containing
1769 reactions and 278 species was established and validated based
on the mole fraction distributions of n-C10H22, major pyrolysis species, and important intermediates
measured in pure fuel and initiated pyrolysis. The kinetic model can
accurately predict the experimental data, and the mechanism of 1-C3H7NO2-initiated pyrolysis of n-C10H22 is analyzed with the model.
The effect of 1-C3H7NO2 on the consumption
of n-C10H22 and selectivity
of cracked products is highlighted.