MMCT energy change in cyanidometal-bridged trinuclear complexes by changing the ligand electron donating ability

Wang, Qian; Liu, Xiaolin; Tan, Bing-Chang; Song, Ying; Jiang, Long-Long; Wu, Xin‐Tao; Sheng, Tian-Lu

doi:10.1039/d2nj06104j

New J. Chem.

2023

DOI: 10.1039/d2nj06104j

|View full text |Cite

MMCT energy change in cyanidometal-bridged trinuclear complexes by changing the ligand electron donating ability

Qian Wang

Xiaolin Liu

Bing-Chang Tan

et al.

Abstract: To investigate the effect of metal to metal charge transfer (MMCT) in the complexes of cyanidometal-bridges, we synthesized and fully characterized a series of trimetallic cyanidometal-bridged compounds with the formula...

Help me understand this report

Search citation statements

Order By: Relevance

Paper Sections

Select...

Citation Types

Supporting

Mentioning

Contrasting

Year Published

2024

Publication Types

Select...

Article2

Relationship

Self Cite1

Independent1

Authors

Journals

Cited by 2 publications

References 62 publications

Supporting

Mentioning

Contrasting

Order By: Relevance

Azo‐Cyanamide Bridged Dinuclear Iron Complexes Exhibiting no Electronic Coupling but Moderate Magnetic Coupling between the two Iron Centers

Mao,

Fu,

et al. 2024

ChemPhysChem

Self Cite

View full text Add to dashboard Cite

To investigate the effect of long‐distance organic ligand on electronic coupling between metallic atoms, the mononuclear and dinuclear complexes [Cp(dppe)Fe(apc)] (1), [{Cp(dppe)Fe}2(μ‐adpc)] (2), [{CpMe5(dppe)Fe}2(μ‐adpc) (3) and their oxidized complexes [Cp(dppe)Fe(apc)][PF6] (1[PF6]), [{Cp(dppe)Fe}2(μ‐adpc)][PF6] (2[PF6]2), [{CpMe5(dppe)Fe}2(μ‐adpc)][PF6]2 (3[PF6]2) (Cp= 1,3‐cyclopentadiene, CpMe5 = 1,2,3,4,5‐pentamethylcyclopentadiene, dppe = 1,2‐bis(diphenylphosphino)ethane), apc‐ = 4‐azo(phenylcyanamido)benzene and adpc2‐ = 4,4′‐azodi(phenylcyanamido)) were synthesized and characterized by cyclic voltammetry, UV‐vis, single‐crystal X‐ray diffraction and Mössbauer spectra. Electrochemical measurements showed no electronic coupling between the two terminal Fe units, However, the investigation results of the magnetic properties of the two‐electron oxidized complexes indicate the presence of moderate antiferromagnetic coupling across 18Å distance.

show abstract

Azo‐Cyanamide Bridged Dinuclear Iron Complexes Exhibiting no Electronic Coupling but Moderate Magnetic Coupling between the two Iron Centers

Mao,

Fu,

et al. 2024

ChemPhysChem

Self Cite

View full text Add to dashboard Cite

show abstract

Cyanido-Bridged Mixed-Valence System: How to Control the Electron Transfer Process

Yang,

Liu,

et al. 2024

Fundamental Research

View full text Add to dashboard Cite

scite is a Brooklyn-based organization that helps researchers better discover and understand research articles through Smart Citations–citations that display the context of the citation and describe whether the article provides supporting or contrasting evidence. scite is used by students and researchers from around the world and is funded in part by the National Science Foundation and the National Institute on Drug Abuse of the National Institutes of Health.

Contact Info

customersupport@researchsolutions.com

10624 S. Eastern Ave., Ste. A-614

Henderson, NV 89052, USA

This site is protected by reCAPTCHA and the Google Privacy Policy and Terms of Service apply.

Blog Terms and Conditions API Terms Privacy Policy Contact Cookie Preferences Do Not Sell or Share My Personal Information

Made with 💙 for researchers

Part of the Research Solutions Family.

MMCT energy change in cyanidometal-bridged trinuclear complexes by changing the ligand electron donating ability

Abstract: To investigate the effect of metal to metal charge transfer (MMCT) in the complexes of cyanidometal-bridges, we synthesized and fully characterized a series of trimetallic cyanidometal-bridged compounds with the formula...

Cited by 2 publications

References 62 publications

Azo‐Cyanamide Bridged Dinuclear Iron Complexes Exhibiting no Electronic Coupling but Moderate Magnetic Coupling between the two Iron Centers

Azo‐Cyanamide Bridged Dinuclear Iron Complexes Exhibiting no Electronic Coupling but Moderate Magnetic Coupling between the two Iron Centers

Cyanido-Bridged Mixed-Valence System: How to Control the Electron Transfer Process

Contact Info

Product

Resources

About