“…In the first attempt, the semi-empirical M-shell X-ray production cross sections have been calculated by defining the normalized cross sections in the usual manner as S ¼ s exp / s ECPSSR , where s ECPSSR refers to our theoretical results of Mshell X-ray production cross sections calculated within the ECPSSR model by using the exact limits of integration (Liu & Cipolla, 1996) and the unperturbed nonrelativistic screened hydrogenic wave functions defined by Choi (1973) to evaluate the form factor (Johnson, Basbas, & McDaniel, 1979) and s exp refers to the experimental cross sections at our disposal of elements with atomic number 72 Z 2 90 collected from different sources (Cipolla, 1995;Goudarzi et al, 2006;Mehta et al, 1982Mehta et al, , 1983Pajek et al, 1990aPajek et al, , 2006RodriguezFern andez et al, 2002;Sera et al, 1980) (528 data points). Also, because of the non availability of the coefficients of CostereKronig and the fluorescence yields of the M i -subshells, necessary to convert the ionization cross sections to the X-ray production ones and vice versa, we used the ratios of the total X-ray production cross sections instead of the total ionization ones.…”