A newly observed isomeric intruder 1 /2 + state [T1 /2 = 3.5(6) ms] is identified in 203 At using a gas-filled recoil separator and fusion-evaporation reactions. The isomer is depopulated through a cascade of E3 and mixed M1/E2 transitions to the 9 /2 − ground state, and it is suggested to originate from the π (s1 /2 ) −1 configuration. In addition, the structures above the 1 /2 + state in 203 At and 197 At are studied using in-beam γ -ray spectroscopy, recoil-decay tagging, and recoil-isomer decay tagging methods. The 1 /2 + state is fed from 3 /2 + and 5 /2 + states, and the origin of these states are discussed.