Mn(III)-Porphyrin Immobilized on the Graphene Oxide-Magnetite Nanocomposite as an Efficient Heterogeneous Catalyst for the Epoxidation of Alkenes

Conjugated porphyrin polymer films with nickel single sites for the electrocatalytic oxygen evolution reaction

“…40,42 Yet, it is essential to ensure the efficient transport of electrons to the catalytic centres to promote high current densities. 43 In this context, several strategies have been exploited to develop metalloporphyrin-based materials with improved optoelectronic and catalytic properties, including the immobilization of metalloporphyrins onto different conductive materials such as carbon nanotubes (CNTs), 39,44,45 graphene oxide (GO) 46,47 and indium or uorinedoped tin oxide (ITO/FTO). 30,48 The polymerization of metalloporphyrins is also a convenient approach to enhance their photo-electrochemical properties.…”

Supramolecular hybrids based on Ru(ii) porphyrin and octahedral Mo(ii) iodide cluster

“…[18][19][20][21] Lately, multicomponent porphyrin hybrid architectures composed of more than two molecular units have become a focus of interest. 22,23 Several strategies have been used to create such supramolecular aggregates, the most common being the formation of metal-directed coordination bonds. 19,[23][24][25] In this case, self-assembly synthesis has the advantage of being thermodynamically driven, and sophisticated molecular architectures can be rapidly assembled from appropriate building blocks under mild conditions.…”

“…22,23 Several strategies have been used to create such supramolecular aggregates, the most common being the formation of metal-directed coordination bonds. 19,[23][24][25] In this case, self-assembly synthesis has the advantage of being thermodynamically driven, and sophisticated molecular architectures can be rapidly assembled from appropriate building blocks under mild conditions. Inspired by this approach, we have recently combined, in a single system, 26 an A 2 -type zinc porphyrin, 5,15-bis[( ptolyl)porphyrinato (2-)]zinc, and an octahedral Mo(II) iodide cluster functionalized with pendant isonicotinate moieties ((Bu 4 N) 2 [{Mo 6 I 8 }(OOC-C 5 H 4 N) 6 ]) (PyMoC).…”

Functionalized MCM-41 based recyclable catalyst for the epoxidation of alkenes using tert-BuOOH

“…Fe2O3 [30], graphene oxide [31] and metal-organic frameworks [32]. Among all of them mesoporous MCM-41 received much interest due to its hexagonal mesoporous channels, uniform pore size distribution, high stability and surface area since the researchers developed M41S family at Mobil Corporation in early 1990s [33].…”