[Mn(terpy)Sb2S4]n, a 1D Network of MnSb4S5 Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Danker, Felix; Anderer, Carolin; Poschmann, Michael; Terraschke, Huayna; Näther, Christian; Leusen, Jan van; Bensch, Wolfgang; Kögerler, Paul

doi:10.1002/ejic.202000225

Eur J Inorg Chem

2020

DOI: 10.1002/ejic.202000225

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[Mn(terpy)Sb₂S₄]_n, a 1D Network of MnSb₄S₅ Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Felix Danker

Carolin Anderer

Michael Poschmann

et al.

Abstract: The solvothermal reaction of an aqueous solution of Na 3 SbS 3 or Schlippe's Salt (Na 3 SbS 4 ·9H 2 O) in the presence of Mn(ClO 4 ) 2 ·6H 2 O and terpy (terpy = 2,2′:6′,2′′-terpyridine) or the [Mn(terpy)] 2+ complex led to crystallization of the new compound [Mn(terpy)Sb 2 S 4 ] n (I). The unique crystal structure of I features chains formed by fused MnSb 4 S 5 rings. The Mn 2+ cation is coordinated by one terpy ligand and two S 2anions resulting in a distorted MnN 3 S 2 trigonal bipyramid. The terpy ligands … Show more

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Cited by 7 publications

References 81 publications

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Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

Zhou,

Qi,

Liu

et al. 2024

Adv Funct Materials

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Research on organic–inorganic hybrid materials (OIHMs) has experienced explosive growth in the past decades. The diversity of organic components allows for the introduction of various spatial scales, functional groups, and polarities, while inorganic components provide higher hardness, heat resistance, and stability, their flexible combination facilitates the formation of diverse structures. Furthermore, simple and cost‐effective synthesis methods, such as room temperature solution processes and mechanochemical techniques, enable precise control over the materials' properties at different scales, thus achieving adjustable structure–performance relationships. This review will discuss the recent research progress of OIHMs within the field of optoelectronics and related optoelectronic device applications. According to the dimension of inorganic components and the nature of organic–inorganic interface, this review divides OIHMs into four structural categories. The ongoing research has revealed diverse applications for OIHMs in the fields of solar cells, light‐emitting devices, detectors, and memristors. As an outlook, the potential of perovskite and 0D metal halide materials, which are currently the most studied, for enhancing optoelectronic performance and stability is discussed.

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Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

Zhou,

Qi,

Liu

et al. 2024

Adv Funct Materials

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BaS:MnS:Sb₂S₅ Mixed Metal Chalcogenide Cubes: Synthesis, Characterization, and Exploring Energy Storage and Production Potential

Ahmad,

Jaffri,

Al‐Hawadi

et al. 2024

Applied Organom Chemis

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Energy‐efficient semiconducting BaS:MnS:Sb2S5 has been synthesized using a single source precursor method. The resulting dithiocarbamate metallic sulfide has an average crystallite size of 17.77 nm and a small band gap of 3.82 eV. A functional group investigation revealed the presence of several bonds, including the metal sulfide bond. This sulfide exhibited a double‐step thermal breakdown pattern. BaS:MnS:Sb2S5 particles were formed like cubes and tended to form cube‐like formations. The electrochemical charge‐storing behavior of BaS:MnS:Sb2S5 was investigated using a nickel foam electrode and a sulfide slurry. The fabricated electrode demonstrated a satisfactory capacity for charge storage, with a specific capacitance of 762.83 F g−1. This indicates a substantial amount of potential for long‐term energy storage utilizing electrodes. This electrode has a specific power density of 9084.78 W kg−1 and a low series resistance of (Rs) = 0.71 Ω, as per impedance measurements. Electro‐catalysis produced an OER overpotential and a corresponding Tafel slope of 233 mV and 157 mV/dec from the electrode. Conversely, for HER activity, the obtained overpotential and subsequent Tafel slope were 386 mV and 73 mV dec−1, respectively.

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An Exotic Layered Compound Consisting of Interconnected Arsenato‐Polyoxovanadate Clusters: Thermal and Magnetic Properties and Liquid Phase Exfoliation

et al. 2020

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The compound {[Mn(teta)]4V16As4O42(H2O)}n ⋅ 10 H2O (teta=triethylenetetraamine) was synthesized under solvothermal conditions. The crystal structure consists of layers composed of {V16As4O42} moieties joined by O−Mn−O bridges. The crystal water molecules can be thermally removed and they are reintegrated in humid atmosphere. The water sorption occurs in two steps indicating differing strengths of hydrogen bonding interactions. Investigations of the magnetic properties present evidence that the antiferromagnetic exchange interactions between the spins of the Mn2+ and of the V4+ cations are relatively strong. The magnetocaloric effect could be observed but is relatively small due to the antiferromagnetic exchange. Using liquid phase exfoliation, small crystallites with thicknesses as low as 10 nm could be obtained, while larger crystallites exhibit thicknesses of 20–40 nm.

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[Mn(terpy)Sb₂S₄]_n, a 1D Network of MnSb₄S₅ Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Cited by 7 publications

References 81 publications

Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

BaS:MnS:Sb₂S₅ Mixed Metal Chalcogenide Cubes: Synthesis, Characterization, and Exploring Energy Storage and Production Potential

An Exotic Layered Compound Consisting of Interconnected Arsenato‐Polyoxovanadate Clusters: Thermal and Magnetic Properties and Liquid Phase Exfoliation

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Product

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About

[Mn(terpy)Sb2S4]n, a 1D Network of MnSb4S5 Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

Cited by 7 publications

References 81 publications

Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

Advanced Organic–Inorganic Hybrid Materials for Optoelectronic Applications

BaS:MnS:Sb2S5 Mixed Metal Chalcogenide Cubes: Synthesis, Characterization, and Exploring Energy Storage and Production Potential

An Exotic Layered Compound Consisting of Interconnected Arsenato‐Polyoxovanadate Clusters: Thermal and Magnetic Properties and Liquid Phase Exfoliation

Contact Info

Product

Resources

About

[Mn(terpy)Sb₂S₄]_n, a 1D Network of MnSb₄S₅ Rings Exhibiting a Pronounced Magnetocaloric Effect and Luminescence

BaS:MnS:Sb₂S₅ Mixed Metal Chalcogenide Cubes: Synthesis, Characterization, and Exploring Energy Storage and Production Potential