The significant negative externalities from vehicles' combustion of fossil fuels have the potential to be overcome through the increasing electrification of the transport sector. This transition faces, however, a wide range of externalities from car purchase and use, new technologies and developing infrastructure, and consumer travel behaviour. In this context, this thesis presents an analysis of travel choices, electric vehicle (EV) adoption barriers, and the importance of complementary network infrastructure.Investments in a car or public transport pass could affect later travel modes. Chapter 1 presents a unique sequential choice experiment of 995 respondents that links car and public transport subscription choices to travel mode decisions. The choice analysis results show that EV adoption does not greatly affect mode choices beyond reactions to varied marginal travel costs. Sunk costs (upfront investment price) also have no influence. A mode commitment effect is largely rejected, however, respondents having chosen a mobility device show lower sensitivity to other modes' trip time. EV adoption, though, faces significant barriers; particularly as the market moves beyond early adopters towards mass adoption. Chapter 2 further presents an analysis of the car type preferences of 882 choice experiment respondents. It finds significant but inelastic EV demand regarding purchase prices, however insignificant sensitivity to driving range and driving costs. There is some heterogeneity, however, across respondents. It also shows stable car preferences among existing car owners and regular car users, while those without a car and public transport users are most likely to adopt an EV. A lack of charging network infrastructure is a further hindrance to the adoption of new technologies and suffers from a chicken-and-egg stand-off with charger providers. Chapter 3 analyses a panel of municipal-level data across Norway and demonstrates a significant impact of additional charging station installations on EV registrations. It especially shows the relatively large effect of early infrastructure provision and the long-lasting, path-determining impact of the very first stations.