Abstract. The duration, shape, and background intensity level of pulses of a passively modelocked Nd-glass laser are determined by noncollinear phase-matched four-photon frequency mixing of time-separated fundamental and second-harmonic pulses in a KI crystal. The pulse shape is found to be slightly asymmetric with slower trailing than rising parts. The background intensity level before and behind the main pulse is about 5 x 10" 6 the peak pulse intensity. 42.55, 42.65, 42.80 The application of mode-locked lasers in time-resolved spectroscopic studies requires an accurate analysis of the temporal behaviour of these lasers. Various techniques have been invented to determine the duration, shape, and background energy level of picosecond lasers. Frequently used methods for the measurement of pulse durations are the two-photon fluorescence, the second harmonic, and the Duguay shutter correlation techniques. The temporal shape and duration are measured with streak cameras. These techniques were reviewed in [1][2][3]. Since the publication of these reviews further techniques have been developed for the measurement of pulse durations [4][5][6][7], pulse shapes [8] and background energy contents [9,10]. The shotto-shot pulse fluctuations were analysed in [11]. In this paper we analyse the temporal behaviour of a mode-locked Nd-glass laser by noncollinear phasematched, nonresonant four-photon frequency mixing of its fundamental and second-harmonic pulses. This technique was first applied by Auston [12]. Here the analysis is refined by application of four-photon frequency mixing theory to the determination of pulse duration, shape, and background intensity content. After calibration of the system the duration of picosecond pulses may be measured in single shots.
PACS:
MethodThe fundamental (frequency v L ) and second-harmonic (frequency v P ) wave of a mode-locked Nd-glass laser interact in a nonlinear optical medium by four-photon frequency mixing v P -bv p -v L -»v s . The energy conservation requires v s = 2v p -v L . The angle cp between the interacting laser beams is adjusted to the phasematching condition k p +k p -k L = k s , The pump pulses are time separated by an optical delay line and the energy conversion y\ = WJ W h of laser light at frequency v L to frequency v s is measured versus delay time t D (t u = 0 at optimum temporal overlap of pump pulses in sample, t D >0 when pulse at v L behind pulse at v p ). The schematic arrangement of the interacting light beams is depicted in Fig. 1.