“…In contrast to environmental agency monitoring programs, scientific programs often focus on headwater catchments free of point-sources and with relatively homogeneous landscape types (Fealy et al, 2010;McGonigle et al, 2014), where in-stream processes are often considered to be minimal (Salmon-Monviola et al, 2013). A comparison of export regimes in contrasting catchments representing different landscape types can be performed to investigate the effect of, for example, contrasting dominant land use, dominant flow paths or climate (Outram et al, 2014;Dupas et al, 2017;Minaudo et al, 2017), sometimes aided by the use of models (e.g., Dupas et al, 2016a;Hartmann et al, 2016). In headwater catchments, several studies have highlighted the important role of landscape heterogeneity within hillslopes (Herndon et al, 2015;Musolff et al, 2017), notably the crucial role of reactive zones such as riparian wetlands (Dick et al, 2015;Pinay et al, 2015;Tiwari et al, 2017) in controlling solute export regimes.…”