2023
DOI: 10.1002/etc.5737
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Model‐Assisted Interpretation of 4,4′‐Methylene Dianiline Adsorption on Soils at Micromolar Concentrations

Patrick M. Plehiers,
Lauren Ward,
Robert J. West
et al.

Abstract: Adsorption kinetics and isotherms were determined for 4,4′‐methylene dianiline (MDA) on five diverse soils at nominal concentrations of 0.01–1.0 mg L−1 (nominal soil loading 0.1–40 μg gs−1). The data were used to model the adsorption process based on the two‐step mechanism that is characteristic of the adsorption of aromatic amines, consisting of a physical equilibrium between the aqueous phase and the soil organic matter and a chemical reaction between the adsorbed MDA and reactive sites in the soil organic m… Show more

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