This paper analyzes voltage control method in order to supply high-quality power for stand-alone microgrid. Stand-alone microgrid is composed of battery bank, stand-alone PCS and controllable loads. The main role of stand-alone PCS is to supply high-quality power to loads as main source by using stable voltage method regardless of load conditions. In particularly, output voltage of stand-alone PCS gets severely unbalanced voltage under unbalanced loads. Fundamental positive and negative sequences are transformed by two coordinates transformation which are rotated in each opposite direction, respectively. Each fundamental d-q voltage is regulated by each fundamental PI control. In addition, low-order harmonics are compensated through resonant controllers. Performance of stand-alone microgrid is tested for feasibility, and it is verified that output voltage of THD is improved to 1% from 2.2% under 50 kW balanced load, and is improved to 1.1% from 2.6% under 50 kW unbalanced load.