Nowadays, in the era of Internet of Things, there are many kinds of teaching resources and ways to inquire. However, there are many problems in the selection, allocation, and management of teaching resources, and there is insufficient utilization of resources. Through the management of curriculum allocation and teacher resource allocation of teaching resources, this paper knows that since 2005 to 2011, the number of college-level English excellent courses and municipal-level English excellent courses has increased greatly, but the number of national-level English excellent courses is small. In order to strengthen the allocation and management of English teaching resources, the number of national excellent courses should be increased. According to the comparison ratio between the number of students and the number of English teachers in a university, which is 152 : 1, the number of English teachers is small. Among the 67 English teachers, senior titles accounted for 29.9%. Teachers with postgraduate degrees accounted for 22.4%. Ordinary teachers account for 47.7%. In order to improve the allocation of English teachers, ordinary teachers should be trained to improve the allocation of English teachers. By comparing 9-year-old teachers, 5-year-old teachers, and 1-year-old teachers, it is found that most teachers are more inclined to use teaching materials, teaching aids, and multimedia in choosing English teaching resources. And through the SMART teaching resource optimization model to the English teaching resources exist in the lack of funds, lack of administrators, school leaders do not pay attention to, and insufficient use of resources and other reasons for optimization. By comparing the SMART model with general English teaching, the UTAUT model and SICAS model, it can be seen that the model proposed in this paper has greatly improved students’ English school ability. Through the analysis of general English teaching and the SMART optimization model, UTAUT model, SICAS model precision, recall rate, F1, AUC, accuracy, and other performance, we know that the SMART model proposed in this paper has the best performance and has a good effect on the optimization of teaching resources in English teaching.