Photovoltaic (PV) systems play a crucial role in clean energy systems. Effective maximum power point tracking (MPPT) techniques are essential to optimize their performance. However, conventional MPPT methods exhibit limitations and challenges in real-world scenarios characterized by rapidly changing environmental factors and various operating conditions. To address these challenges, this paper presents a performance evaluation of a novel extended grey wolf optimizer (EGWO). The EGWO has been meticulously designed in order to improve the efficiency of PV systems by rapidly tracking and maintaining the maximum power point (MPP). In this study, a comparison is made between the EGWO and other prominent MPPT techniques, including the grey wolf optimizer (GWO), equilibrium optimization algorithm (EOA), particle swarm optimization (PSO) and sin cos algorithm (SCA) techniques. To evaluate these MPPT methods, a model of a PV module integrated with a DC/DC boost converter is employed, and simulations are conducted using Simulink-MATLAB software under standard test conditions (STC) and various environmental conditions. In particular, the results demonstrate that the novel EGWO outperforms the GWO, EOA, PSO and SCA techniques and shows fast tracking speed, superior dynamic response, high robustness and minimal power fluctuations across both STC and variable conditions. Thus, a power fluctuation of 0.09 W could be achieved by using the proposed EGWO technique. Finally, according to these results, the proposed approach can offer an improvement in energy consumption. These findings underscore the potential benefits of employing the novel MPPT EGWO to enhance the efficiency and performance of MPPT in PV systems. Further exploration of this intelligent technique could lead to significant advancements in optimizing PV system performance, making it a promising option for real-world applications.