The Eddy Dissipation Concept (EDC) is common in modeling turbulent combustion. Several model improvements have been proposed in literature; recent modifications aim to extend its validity to Moderate or Intense Low oxygen Dilution (MILD) conditions. In general, the EDC divides a fluid into a reacting and a non-reacting part. The reacting part is modeled as perfectly stirred reactor (PSR) or plug flow reactor (PFR). EDC theory suggests PSR treatment, while PFR treatment provides numerical advantages. Literature lacks a thorough evaluation of the consequences of employing the PFR fine structure treatment. Therefore, these consequences were evaluated by employing tests to isolate the effects of the EDC variations and fine structure treatment and by conducting a Sandia Flame D modeling study. Species concentration as well as EDC species consumption/production rates were evaluated. The isolated tests revealed an influence of the EDC improvements on the EDC rates, which is prominent at low shares of the reacting fluid. In contrast, PSR and PFR differences increase at large fine fraction shares. The modeling study revealed significant differences in the EDC rates of intermediate species. Summarizing, the PFR fine structure treatment might be chosen for schematic investigations, but for detailed investigations a careful evaluation is necessary.Energies 2018, 11, 1902 2 of 21 mixing rate only, and an infinitely fast chemistry assumption is possible. However, if turbulence and turbulent mixing decrease, the reaction progress can be limited by either mixing or chemistry. In this regime, finite rate chemistry is necessary to accurately describe the turbulence-chemistry interaction [7,12,13]. When using detailed chemistry with the EDC, the fine structures are typically treated as perfectly stirred reactors (PSRs), since educts are mixed on a molecular scale and mass is exchanged with the surroundings [4]. The fine structure state is determined by solving the PSR to steady-state, which is numerically expensive due to the strong nonlinearity in the reaction source terms. Some EDC implementations, therefore, treat the fine structures as plug flow reactors (PFR) [7,[16][17][18][19]. These PFRs are solved for the fine structure residence time, implying that the fine structures are spatially isolated structures in the fluid only evolving in time. Since fine structure residence times are typically small (approx. O 10 −7 to O 10 −3 seconds) for classical turbulent combustion, the numerical effort to solve the detailed chemistry in a PFR is significantly reduced. However, the latter approach is not in line with the EDC theory. Although the PFR fine structure treatment was employed in many published research works, e.g., [16][17][18][19][20][21], only De et al. [17], Li et al. [16], and Lewandowski and Ertesvaag [18] commented on the consequences of the PFR simplification. However, none of them performed an in-depth analysis of species profiles and species consumption rates.De et al. [17] state that the PSR and PFR results are only sim...