“…Long-term changes in N 2 O emissions and tropospheric aN 2 O have been studied and reported for glacial-interglacial variations (Joos et al, 2020;Rubino et al, 2019;Schilt et al, 2010). For the modern period, the N 2 O emissions from terrestrial ecosystems and the oceans have been investigated progressively across scales with site observations (e.g., Kock & Bange, 2015;Pastorello et al, 2020), field experiments (e.g., Breider et al, 2019;Dijkstra et al, 2012), as well as modeling (e.g., Martins et al, 2022;Landolfi et al, 2017;Xu-Ri & Prentice, 2008;Manizza et al, 2012). However, due to the complex processes of N 2 O production in soils, inland waters and oceans (e.g., Battaglia & Joos, 2018;Ma et al, 2022;Hutchins & Capone, 2022) and loss in the stratosphere (Mueller, 2021), there is still poor understanding of the controls on tropospheric aN 2 O and its seasonal and inter-annual variations.…”