Physical aspects of nonuniqueness of shock-wave structures in supersonic and hypersonic flows are considered. Thermodynamic conditions determining the dual solution domains are analyzed, and the boundaries of the transition from Mach to regular reflection are examined.Evolution of mathematical simulation methods due to high-quality performance of advanced computers made it possible to study three-dimensional high-velocity gas flows with complicated shock-wave structures. Investigation of nonuniqueness and hysteresis of numerical solutions obtained and analysis of the degree of their adequacy to real physical processes become more and more important. Nevertheless, the approach based on postulates of mechanics, which sometimes involves too many mathematical details, with an analysis of the classical gas-dynamic Euler equations closed by the equation of state of an ideal gas, still prevails in gas dynamics. The physics of the process (excitation of vibrational and rotational degrees of freedom of molecules, their dissociation, recombination, and ionization of atoms), however, is often ignored. This was more or less admissible in studying supersonic flows because the influence of physical and chemical processes was not very strong, but the effect of these processes on the gas medium with hypersonic velocities can be fairly noticeable.The main objective of the present work is the analysis of shock-wave interaction if a dual solution is possible: both regular and Mach types of interaction of shock waves can exist under identical governing parameters of the problem. The results and conclusions of [1] are also discussed, which involved a comprehensive (experimental and numerical) study of the possibility of "artificially" changing the steady pattern of interaction of shock waves generated by a high-velocity gas flow incident onto a system of two wedges with apex half-angles β 1 and β 2 (Fig. 1), with a transition from Mach reflection of shock waves to regular reflection. For this class of problems, there is a range of parameters [β * , β * * ], in which, under the conditionthe laws of conservation (of mass, momentum, and energy) admit the existence of both Mach and regular reflection (Neumann paradox). Outside the range determined by Eq. (1), there can exist only regular reflection ifor only Mach reflection isConditions (1)-(3) are written for the symmetric case β 1 = β 2 = β (see [2] for more details). Intensification of research associated with the development of hypersonic flying vehicles and elements of its engine stimulated the practical interest in studying seemingly purely mathematical problems, such as nonuniqueness and bifurcation of solutions of equations (in our case, gas-dynamic equations).