2007
DOI: 10.1016/j.fluid.2007.05.028
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Modeling of solid–liquid equilibria for systems with solid-complex phase formation

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Cited by 44 publications
(38 citation statements)
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“…1 the solid-liquid-vapor state diagram for the water-phenol system as reported recently by Tumakaka et al [11] is shown. The origin of the experimental data is from Ref.…”
Section: Separation By Steam Distillationsupporting
confidence: 52%
See 1 more Smart Citation
“…1 the solid-liquid-vapor state diagram for the water-phenol system as reported recently by Tumakaka et al [11] is shown. The origin of the experimental data is from Ref.…”
Section: Separation By Steam Distillationsupporting
confidence: 52%
“…Reprinted with permission from Ref. [11]. phenols are pharmaceutical, plastics, wood products, paint, and pulp and paper industries (0.1-1600 mg/l).…”
Section: Abatement Technologies For Phenol In Wastewatersmentioning
confidence: 99%
“…Moreover, the model was proven to give a good prediction of phase behavior in multicomponent systems based on the knowledge of pure component or binary data only. Recently, PC-SAFT was also successfully applied to calculate solid-liquid equilibria of mixtures with amino acids [24] and systems with complex formation in the solid phase [25].…”
Section: Introductionmentioning
confidence: 99%
“…By complex phase equilibrium we mean equilibrium scenarios in which three or more phases can coexist. To illustrate the capability of the EA method for complex phase equilibrium calculations, we selected the binary mixture of water and phenol recently reported by Tumakakaa et al 15 as a test case. This binary mixture is used in particular crystallization processes; for these crystallization processes, LLE and VLE is of particular concern during purification.…”
Section: Applications Of the Ea Methodsmentioning
confidence: 99%
“…The second row of Tables 2 and 3 show the regressed values for the parameters as well as the absolute average deviations (AAD) of the predictions from those generated by DIPPR. The binary interaction parameter (k 12 ¼ 0.013) was fitted using experimental LLE data extracted from Tumakakaa et al 15 as shown in Figure 10. With these parameters, we calculated the complete phase diagram in this figure. Comparing the AAD values for the PC-SAFT and FMSA-SAFT models in Tables 2 and 3 and comparing the equilibrium curves in Figure 10, shows that FMSA-SAFT is slightly better in AADs due to parameter regression but there is little difference between the two models in Figure 10 for this highly associating mixture.…”
Section: Applications Of the Ea Methodsmentioning
confidence: 99%