This article describes the modelling software complexes are described that allow to determine such parameters of technological processes that can not be directly measured, but knowledge of which is necessary for conducting chemical processes in optimal modes for a given quality of the product. The imitation modelling software of the polymerization of vinyl chloride, which allows determining the molecular mass distribution of polymer molecules, describes a program for modelling the electrolyzer parameters in the production of sodium hydroxide, chlorine and hydrogen, based on the temperature dependence of the current-voltage characteristic. The imitating modelling software of the polymerization process of vinyl chloride allows to determine the physical-chemical properties of polyvinyl chloride in the polymerization process, will help to ensure optimal modes of technological processes, to predict the change in parameters in the event of abnormal situations, which will increase the level of trouble-free functioning.In the training and monitoring modes of operation with the help of imitation software, it is possible to quickly assess the level of training of personnel, and also, if necessary, to conduct their training on the basis of the modules of virtual reproduction of the technological process included in it.Using the developed simulation-modelling software of the process of electrolysis of sodium hydroxide, chlorine and hydrogen production, it is possible to model the temperature dependence of the current-voltage characteristic, which helps to ensure optimal modes of technological processes, to predict the change in parameters in the event of abnormal situations, which will increase the level of troublefree operation.