Solar thermochemical reactor provides an attractive approach that utilizes the most common solar radiation as the thermal driving force to motivate the reaction between CO2 and metal oxides, which is also called metal oxide redox pair-based thermochemical cycles. The CeO2/CeO2-δ is widely used in the two-step redox process due to its advantages including fast-redox kinetics, high crystallographic stability of a wide range of reacting oxygen non-stoichiometry, and relatively high oxygen solid-state conductivity. In this work, a three-dimensional transient numerical analysis has been completed to study the performance of a CeO2 reduction reaction in a 1/8th segment region of a novel partition cavity-receiver reactor. The porous CeO2 catalyst was analyzed using the discrete element method (DEM) to capture the heat transfer and reactive performances. The catalyst textural properties (particle size and void fraction) and reaction conditions (gas flow rate and radiative power input) were investigated in the CeO2 reduction reaction. The results indicated that increasing the catalyst specific surface area and the temperature are beneficial to the O2 production and further CO2 conversion.