The pursuit of sustainable and environmentally friendly transportation has led to the exploration of alternative fuel sources, among which hydrogen stands out prominently. This work delves into the potential of hydrogen fuel for internal combustion engines (ICEs), emphasizing its capacity to ensure the required performance levels while concurrently enhancing overall efficiency. The integration of a mild hybrid powertrain in a small size passenger car was considered for obtaining a twofold advantage: mitigating power loss due to low volumetric efficiency and increasing fuel economy. A comprehensive approach combining 0D/1D modeling simulations and experimental validations was employed on a gasoline-powered small size ICE, considering its conversion to hydrogen, and mild hybridization. Vehicle simulations were performed in AVL Cruise M and validated against experimental data. Various electric motors were scrutinized for a small size battery pack typical of mild hybrid vehicles. Furthermore, the paper assesses the potential range achievable with the hydrogen-powered hybrid vehicle and compares it with the range reported by the manufacturer for the original gasoline and pure electric version. In terms of global results, these modifications were found to successfully improve efficiency compared to baseline gasoline and hydrogen fueling. Additionally, performance gains were achieved, surpassing the capabilities of the original gasoline vehicle despite its intrinsic volumetric efficiency limitations when using hydrogen. Along with the conversion to hydrogen and thus zero-carbon tail-pipe emissions, incorporating a Start/Stop system, and the integration of mild hybrid technology with energy recuperation during braking, overall efficiency was enhanced by up to 30% during urban use. Furthermore, the hybridization implemented in the H2 version allows an autonomy comparable to that of the electric vehicle but with evident shorter refilling times. Specific aspects of the 48 V battery management are also scrutinized.